Conductivity of sodium chloride in water+1,4-dioxane mixtures at temperatures from 5 to 35°C -: I.: Dilute solutions

被引:90
作者
Bester-Rogac, M [1 ]
Neueder, R [1 ]
Barthel, J [1 ]
机构
[1] Univ Regensburg, Inst Phys & Theoret Chem, D-93040 Regensburg, Germany
关键词
electrolyte conductivity; ionic conductivities; sodium chloride; water-dioxane mixtures;
D O I
10.1023/A:1022625310402
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The molar and single-ion conductivities of dilute solutions of sodium chloride (C < 0.01 mol-dm(-3)) in binary mixtures of 1,4-dioxane with water were measured covering a broad solvent composition range at temperatures from 5 to 35 degrees C. Accurate viscosity and permittivity data were determined for the organic solvent system. Evaluation of the limiting molar conductivity Lambda(infinity), ionic conductivities lambda(+)(infinity), and lambda(-)(infinity), and the association constant K-A is based on the chemical model of electrolyte solutions, including short-range forces.
引用
收藏
页码:1071 / 1086
页数:16
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