Hydroamination of alkynes catalyzed by a titanium pyrrolyl complex

被引：127

作者：

Cao, CS ^{[1
]}

Ciszewski, JT ^{[1
]}

Odom, AL ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 24期

关键词：

D O I：

10.1021/om010595m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The readily prepared pyrrolyl complex Ti(NMe2)(2)(dpma), where dpma is di(pyrrolyl-alpha -methyl)methylamine, is an effective precatalyst for the hydroamination of alkynes by primary amines. The catalysis is Markovnikov-selective and rapid with terminal alkynes.

引用

页码：5011 / 5013

页数：3

共 49 条

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