Separation of hydrocarbons with a microporous metal-organic framework

被引：731

作者：

Pan, L ^{[1
]}

Olson, DH ^{[1
]}

Ciemnolonski, LR ^{[1
]}

Heddy, R ^{[1
]}

Li, J ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Biol Chem, Piscataway, NJ 08854 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 04期

关键词：

adsorption; hydrocarbons; hydrothermal synthesis; microporous materials;

D O I：

10.1002/anie.200503503

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Separating the wheat from the chaff: The microporous metal-organic framework (MMOF) of [Cu(hfipbb)(H2hfipbb)0.5] is based on a bimetallic paddle-wheel building block and comprises 1D tubular microchannels formed by the interpenetration of two identical 44 nets. The channels are hydrophobic and have the ideal size and shape to selectively adsorb C 2, C3, and n-C4 olefins and alkanes (see picture). (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：616 / 619

页数：4

共 37 条

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