Layer-by-layer processed high-performance polymer solar cells

被引：23

作者：

Li, Hui ^{[1
]}

Wang, Jizheng ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China

来源：

APPLIED PHYSICS LETTERS | 2012年 / 101卷 / 26期

基金：

中国国家自然科学基金;

关键词：

OPEN-CIRCUIT VOLTAGE; BULK-HETEROJUNCTION; PHOTOVOLTAIC DEVICES; BILAYER; MORPHOLOGY; EFFICIENCY; HETEROSTRUCTURE; POLYTHIOPHENE; ENHANCEMENT; MISCIBILITY;

D O I：

10.1063/1.4773515

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Layer-by-layer (LL) process has great potential in achieving high-performance polymer solar cells (PSCs) due to its advantage in realizing p-i-n like structure. LL method is attracting more and more interests in fabricating PSCs, and power conversion efficiency (PCE) of LL processed PSCs has been greatly improved to over 5% recently. In this paper, by employing LL approach, we fabricated polymer photovoltaic devices with poly(3-hexylthiophene) (P3HT) as donor and four different fullerenes as acceptor. PCE of 6.48% was achieved. Performances of the LL processed devices are comparatively better than that of their corresponding traditional bulk-heterojunction devices. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4773515]

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页数：5

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共 51 条

[1]

[Anonymous], PHYS SEMICONDUCTOR D

[2] Reappraising the Need for Bulk Heterojunctions in Polymer-Fullerene Photovoltaics: The Role of Carrier Transport in All-Solution-Processed P3HT/PCBM Bilayer Solar Cells [J].

Ayzner, Alexander L. ;

Tassone, Christopher J. ;

Tolbert, Sarah H. ;

Schwartz, Benjamin J. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (46) :20050-20060

[3] Physical chemical principles of photovoltaic conversion with nanoparticulate, mesoporous dye-sensitized solar cells [J].

Bisquert, J ;

Cahen, D ;

Hodes, G ;

Rühle, S ;

Zaban, A .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (24) :8106-8118

[4] Bilayer heterojunction polymer solar cells using unsubstituted polythiophene via oxidative chemical vapor deposition [J].

Borrelli, David C. ;

Barr, Miles C. ;

Bulovic, Vladimir ;

Gleason, Karen K. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 99 :190-196

[5] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Brabec, Christoph J. ;

Gowrisanker, Srinivas ;

Halls, Jonathan J. M. ;

Laird, Darin ;

Jia, Shijun ;

Williams, Shawn P. .

ADVANCED MATERIALS, 2010, 22 (34) :3839-3856

[6] External quantum efficiency versus charge carriers mobility in polythiophene/methanofullerene based planar photodetectors [J].

Caironi, M. ;

Agostinelli, T. ;

Natali, D. ;

Sampietro, M. ;

Cugola, R. ;

Catellani, M. ;

Luzzati, S. .

JOURNAL OF APPLIED PHYSICS, 2007, 102 (02)

[7] Poly-(3-hexylthiophene)/[6,6]-phenyl-C61-butyric-acid-methyl-ester bilayer deposition by matrix-assisted pulsed laser evaporation for organic photovoltaic applications [J].

Caricato, A. P. ;

Cesaria, M. ;

Gigli, G. ;

Loiudice, A. ;

Luches, A. ;

Martino, M. ;

Resta, V. ;

Rizzo, A. ;

Taurino, A. .

APPLIED PHYSICS LETTERS, 2012, 100 (07)

[8] Bulk Heterojunction Photovoltaic Active Layers via Bilayer Interdiffusion [J].

Chen, Dian ;

Liu, Feng ;

Wang, Cheng ;

Nakahara, Atsuhiro ;

Russell, Thomas P. .

NANO LETTERS, 2011, 11 (05) :2071-2078

[9] Polymer solar cells with enhanced open-circuit voltage and efficiency [J].

Chen, Hsiang-Yu ;

Hou, Jianhui ;

Zhang, Shaoqing ;

Liang, Yongye ;

Yang, Guanwen ;

Yang, Yang ;

Yu, Luping ;

Wu, Yue ;

Li, Gang .

NATURE PHOTONICS, 2009, 3 (11) :649-653

[10] The miscibility and depth profile of PCBM in P3HT: thermodynamic information to improve organic photovoltaics [J].

Chen, Huipeng ;

Hegde, Raghavendra ;

Browning, J. ;

Dadmun, M. D. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (16) :5635-5641

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