Mixed-anion complexes with a bipyrazolyl ligand. A new entry to a realm of three-dimensional five-connected coordination topologies

被引：50

作者：

Ponomarova, VV

Komarchuk, VV

Boldog, I

Chernega, AN

Sieler, J

Domasevitch, KV

机构：

[1] Natl Taras Shevchenko Univ Kiev, Dept Inorgan Chem, UA-01033 Kiev, Ukraine

[2] Inst Organ Chem, UA-253660 Kiev, Ukraine

[3] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 05期

关键词：

D O I：

10.1039/b110599j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cross-linking of corrugated square grid coordination layers by anionic bridging groups generates five-connected coordination networks; the 3D topologies of mixed-anion cobalt(II) and nickel(II) complexes with a tetramethyl-substituted 4,4'-bipyrazolyl ligand are supported by mu-SO42- functions and exist as neutral or cationic five-connected arrays involving additional terminal (NCS-) or non-coordinated (NO3-, ClO4-) groups.

引用

页码：436 / 437

页数：2

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