Neptunium(VI) chain and neptunium(VI/V) mixed valence cluster complexes

被引：44

作者：

Cornet, Stephanie M. ^{[2
]}

Haeller, L. Jonas L. ^{[3
]}

Sarsfield, Mark J. ^{[4
]}

Collison, David ^{[5
]}

Helliwell, Madeleine ^{[5
]}

May, Iain ^{[1
]}

Kaltsoyannis, Nikolas ^{[3
]}

机构：

[1] Los Alamos Natl Lab, Los Alamos, NM 87544 USA

[2] Univ Manchester, Ctr Radiochem Res, Sch Chem, Manchester M13 9PL, Lancs, England

[3] UCL, Dept Chem, London WC 1H, England

[4] UK Natl Nucl Lab, Cent Lab, Seascale CA20 1PG, Cumbria, England

[5] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 08期

基金：

英国工程与自然科学研究理事会; 美国能源部;

关键词：

CATION-CATION INTERACTIONS; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURES; NEPTUNYL CHLORIDE; COORDINATION; DISPROPORTIONATION; ABSORPTION; REDUCTION; CHEMISTRY; BOND;

D O I：

10.1039/b818973k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of [(NpO2Cl2)-O-VI(thf)](n) offers the potential for more detailed exploration of neptunyl(VI) chemistry, while the synthesis of the mixed valence cluster complex[{(NpO2Cl2)-O-VI}{(NpO2Cl)-O-V(thf)(3)}(2)] allows molecular neptunyl(V) 'cation-cation' interactions to be probed.

引用

页码：917 / 919

页数：3

共 36 条

[21] Biological reduction of Np(V) and Np(V) citrate by metal-reducing bacteria
Icopini, Gary A.
Boukhalfa, Hakim
Neu, Mary P.
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (08) : 2764 - 2769
[22] Krot N.N., 2004, Russ. Chem. Rev, V73, P89, DOI DOI 10.1070/RC2004v073n01ABEH000852
[23] Nash K.L., 2006, Actinide Separation Science and Technology The Chemistry of the Actinide and Transactinide Elements, P2622, DOI [DOI 10.1007/1-4020-3598-5_24, 10.1007/1-4020-3598-5_24]
[24] On the inverse trans influence.: Density functional studies of [MOX5]n- (M = Pa, n=2; M = U, n=1; M = Np, n=0; X = F, Cl or Br)
O'Grady, E
Kaltsoyannis, N
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06): : 1233 - 1239
[25] Solubility and sorption of redox-sensitive radionuclides (Np, Pu) in J-13 water from the Yucca Mountain site: comparison between experiment and theory
Runde, W
Conradson, SD
Efurd, DW
Lu, NP
VanPelt, CE
Tait, CD
[J]. APPLIED GEOCHEMISTRY, 2002, 17 (06) : 837 - 853
[26] Neptunium(V) disproportionation and cation-cation interactions in TBP/kerosene solvent
Sarsfield, M. J.
Taylor, R. J.
Maher, C. J.
[J]. RADIOCHIMICA ACTA, 2007, 95 (12) : 677 - 682
[27] Preference for nitrogen versus oxygen donor coordination in uranyl-and neptunyl(VI) complexes
Sarsfield, MJ
May, I
Cornet, SM
Helliwell, M
[J]. INORGANIC CHEMISTRY, 2005, 44 (21) : 7310 - 7312
[28] Distorted equatorial coordination environments and weakening of U=O bonds in uranyl complexes containing NCN and NPN ligands
Sarsfield, MJ
Helliwell, M
Raftery, J
[J]. INORGANIC CHEMISTRY, 2004, 43 (10) : 3170 - 3179
[29] Extending the chemistry of the uranyl ion: Lewis acid coordination to a U=O oxygen
Sarsfield, MJ
Helliwell, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (04) : 1036 - 1037
[30] The first uranyl-methine carbon bond; a complex with out-of-plane uranyl equatorial coordination
Sarsfield, MJ
Helliwell, M
Collison, D
[J]. CHEMICAL COMMUNICATIONS, 2002, (19) : 2264 - 2265

← 1 2 3 4 →