Mechanochemical reactions and syntheses of oxides

被引:272
作者
Sepelak, Vladimir [1 ,2 ]
Duevel, Andre [2 ,3 ]
Wilkening, Martin
Becker, Klaus-Dieter [2 ,4 ,5 ]
Heitjans, Paul [2 ,3 ]
机构
[1] Karlsruhe Inst Technol, Inst Nanotechnol, D-76344 Eggenstein Leopoldshafen, Germany
[2] Leibniz Univ Hannover, Ctr Solid State Chem & New Mat, D-30167 Hannover, Germany
[3] Leibniz Univ Hannover, Inst Phys Chem & Electrochem, D-30167 Hannover, Germany
[4] Graz Univ Technol, Inst Chem & Technol Mat, A-8010 Graz, Austria
[5] Braunschweig Univ Technol, Inst Phys & Theoret Chem, D-38106 Braunschweig, Germany
关键词
NONEQUILIBRIUM CATION DISTRIBUTION; CANTED SPIN ARRANGEMENT; ENHANCED MAGNETIZATION; MECHANICAL ACTIVATION; STRUCTURAL DISORDER; MGAL2O4; SPINEL; NANOCRYSTALLINE; MECHANOSYNTHESIS; DIFFUSION; REDISTRIBUTION;
D O I
10.1039/c2cs35462d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Technological and scientific challenges coupled with environmental considerations have prompted a search for simple and energy-efficient syntheses and processing routes of materials. This tutorial review provides an overview of recent research efforts in non-conventional reactions and syntheses of oxides induced by mechanical action. It starts with a brief account of the history of mechanochemistry. Ensuing discussions will review the progress in homogeneous and heterogeneous mechanochemical reactions in oxides of various structures. The review demonstrates that the event of mechanically induced reactions provides novel opportunities for the non-thermal manipulation of materials and for the tailoring of their properties.
引用
收藏
页码:7507 / 7520
页数:14
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