Mechanochemistry: The mechanical activation of covalent bonds

被引:1092
作者
Beyer, MK
Clausen-Schaumann, H
机构
[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany
[2] GSF Forschungszentrum Umwelt & Gesundheit GMBH, Inst Strahlenschutz, D-85764 Neuherberg, Germany
[3] Munich Univ Appl Sci, D-80335 Munich, Germany
关键词
D O I
10.1021/cr030697h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Unlike other ways of chemical activation, mechanochemistry is less known. This review gives a survey of the classical works in mechanochemistry and puts the key mechanochemical phenomena into perspective with recent results from atomic force microscopy and quantum molecular dynamics simulations. Focus is on mechanochemical phenomena, where identifiable strong, covalent chemical bonds are activated by the presence of an external mechanical force.
引用
收藏
页码:2921 / 2948
页数:28
相关论文
共 410 条
  • [1] CRYOGENIC DEGRADATION OF POLYSTYRENE IN SOLUTION
    ABBAS, KB
    KIRSCHNER, T
    PORTER, RS
    [J]. EUROPEAN POLYMER JOURNAL, 1978, 14 (05) : 361 - 367
  • [2] Polysaccharide properties probed with atomic force microscopy
    Abu-Lail, NI
    Camesano, TA
    [J]. JOURNAL OF MICROSCOPY, 2003, 212 : 217 - 238
  • [3] PLASTIC-DEFORMATION OF NANOMETER-SCALE GOLD CONNECTIVE NECKS
    AGRAIT, N
    RUBIO, G
    VIEIRA, S
    [J]. PHYSICAL REVIEW LETTERS, 1995, 74 (20) : 3995 - 3998
  • [4] CONDUCTANCE STEPS AND QUANTIZATION IN ATOMIC-SIZE CONTACTS
    AGRAIT, N
    RODRIGO, JG
    VIEIRA, S
    [J]. PHYSICAL REVIEW B, 1993, 47 (18): : 12345 - 12348
  • [5] Plastic deformation in nanometer scale contacts
    Agrait, N
    Rubio, G
    Vieira, S
    [J]. LANGMUIR, 1996, 12 (19) : 4505 - 4509
  • [7] Breaking bonds by mechanical stress: When do electrons decide for the other side?
    Aktah, D
    Frank, I
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (13) : 3402 - 3406
  • [8] DNA:: A programmable force sensor
    Albrecht, C
    Blank, K
    Lalic-Mülthaler, M
    Hirler, S
    Mai, T
    Gilbert, I
    Schiffmann, S
    Bayer, T
    Clausen-Schaumann, H
    Gaub, HE
    [J]. SCIENCE, 2003, 301 (5631) : 367 - 370
  • [9] Stretching DNA and RNA to probe their interactions with proteins
    Allemand, JF
    Bensimon, D
    Croquette, V
    [J]. CURRENT OPINION IN STRUCTURAL BIOLOGY, 2003, 13 (03) : 266 - 274
  • [10] Allen S, 2003, BIOCHEM SOC T, V31, P1052