High pressure synthesis of alkali metal doped C60 polymers

被引：9

作者：

Yasukawa, M ^{[1
]}

Yamanaka, S

机构：

[1] CREST, Japan Sci & Technol Corp, JST, Higashihiroshima 7398527, Japan

[2] Hiroshima Univ, Fac Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1999年 / 7卷 / 05期

关键词：

D O I：

10.1080/10641229909351379

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alkali metal doped fullerenes, AC(60) (A = Li, Na) were polymerized under a pressure of 5 GPa at 573 K. The X-ray diffraction patterns of the products were very similar to that of the rhombohedral two-dimensional C-60, polymer, the basal spacings being slightly increased by the intercalation of the alkali atoms between the two-dimensional polymer layers. The alkali metal doped C-60 polymers were insoluble in toluene and found to be semiconductors over a temperature range of 200 - 300 K.

引用

页码：795 / 806

页数：12

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