Fluorescent Gold Nanoparticle Superlattices

被引:35
作者
Nishida, Naoki [1 ]
Shibu, Edakkattuparambil S.
Yao, Hiroshi [1 ]
Oonishi, Tsugao [1 ]
Kimura, Keisaku [1 ]
Pradeep, Thalappil
机构
[1] Univ Hyogo, Grad Sch Mat Sci, Kamigori, Hyogo 6781297, Japan
关键词
D O I
10.1002/adma.200800632
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
3D superlattices of fluorescent gold nanoparticles are prepared at an air/water interface. The hexagonal assembly extends over several micrometers, and crystals of triangular morphology are imaged using the fluorescence emission of the monolayers protecting the nanoparticles (see figure). Surprisingly, the superlattices are fluorescent even though the fluorescein derivative is close to the metallic core and strong quenching is expected.
引用
收藏
页码:4719 / +
页数:6
相关论文
共 27 条
[1]   Monolayer-protected clusters with fluorescent dansyl ligands [J].
Aguila, A ;
Murray, RW .
LANGMUIR, 2000, 16 (14) :5949-5954
[2]   SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].
BRUST, M ;
WALKER, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
WHYMAN, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802
[3]   Synthesis and characterization of carboxylate-modified gold nanoparticle powders dispersible in water [J].
Chen, SH ;
Kimura, K .
LANGMUIR, 1999, 15 (04) :1075-1082
[4]   Gold nanoelectrodes of varied size: Transition to molecule-like charging [J].
Chen, SW ;
Ingram, RS ;
Hostetler, MJ ;
Pietron, JJ ;
Murray, RW ;
Schaaff, TG ;
Khoury, JT ;
Alvarez, MM ;
Whetten, RL .
SCIENCE, 1998, 280 (5372) :2098-2101
[5]   Dynamic and static quenching of fluorescence by 1-4 nm diameter gold monolayer-protected clusters [J].
Cheng, PPH ;
Silvester, D ;
Wang, GL ;
Kalyuzhny, G ;
Douglas, A ;
Murray, RW .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (10) :4637-4644
[6]   Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J].
Daniel, MC ;
Astruc, D .
CHEMICAL REVIEWS, 2004, 104 (01) :293-346
[7]   Fluorescence quenching of dye molecules near gold nanoparticles:: Radiative and nonradiative effects -: art. no. 203002 [J].
Dulkeith, E ;
Morteani, AC ;
Niedereichholz, T ;
Klar, TA ;
Feldmann, J ;
Levi, SA ;
van Veggel, FCJM ;
Reinhoudt, DN ;
Möller, M ;
Gittins, DI .
PHYSICAL REVIEW LETTERS, 2002, 89 (20) :203002-203002
[8]   Selective colorimetric detection of polynucleotides based on the distance-dependent optical properties of gold nanoparticles [J].
Elghanian, R ;
Storhoff, JJ ;
Mucic, RC ;
Letsinger, RL ;
Mirkin, CA .
SCIENCE, 1997, 277 (5329) :1078-1081
[9]   Energy transfer from a surface-bound arene to the gold core in ω-fluorenyl-alkane-1-thiolate monolayer-protected gold clusters [J].
Gu, T ;
Whitesell, JK ;
Fox, MA .
CHEMISTRY OF MATERIALS, 2003, 15 (06) :1358-1366
[10]   Three-dimensional hexagonal close-packed superlattice of passivated Ag nanocrystals [J].
Harfenist, SA ;
Wang, ZL ;
Whetten, RL ;
Vezmar, I ;
Alvarez, MM .
ADVANCED MATERIALS, 1997, 9 (10) :817-&