Supramolecular self-organization in methyl(diphenylphosphinothioato)mercury(II), [HgMe{S(O)PPh(2)}], a polymer containing Hg2O2P2S2 eight-membered rings interconnected through secondary Hg center dot center dot center dot O bonds

被引：20

作者：

Casas, JS

Castineiras, A

Haiduc, I

Sanchez, A

Sordo, J

VazquezLopez, EM

机构：

[1] Facultatea de Chimie, Universitatea Babes-Bolyai

[2] Depto. de Quim. Inorgánica, Facultade de Farmacia, Univ. de Santiago de Compostela

来源：

POLYHEDRON | 1997年 / 16卷 / 05期

关键词：

supramolecular chemistry; methylmercury(II); phenylmercury(II); phosphinothioates; X-ray structure; multinuclear NMR;

D O I：

10.1016/S0277-5387(96)00344-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methyl- and phenylmercury(II) diphenylphosphinothioates [HgR{S(O)PPh(2)}] (R = Me and Ph) were synthesized. In [HgMe{S(O)PPh(2)}] the mercury atom is coordinated to the methyl carbon atom and to the ligand sulfur atom. Intermolecular Hg ... O interactions form a supramolecular ribbon structure along the b-axis. The IR and NMR (H-1, C-13, P-31 and Hg-199) spectra of the two compounds are discussed. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：781 / 787

页数：7

共 24 条

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Alcock N.W., 1972, ADV INORG CHEM, V15, P1, DOI DOI 10.1016/S0065-2792(08)60016-3

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