Modulation of breathing behavior of layered coordination polymers via a solid solution approach: the influence of metal ions on sorption behavior

被引：28

作者：

Mukherjee, Gargi ^{[1
]}

Biradha, Kumar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 06期

关键词：

ORGANIC FRAMEWORKS; CORE; TRANSMETALATIONS; MOLECULES; CRYSTAL; MIL-53;

D O I：

10.1039/c3cc48020h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four iso-structural layered coordination polymers (CPs) of Cd(II) and Zn(II) were shown to exhibit breathing transitions with N-2/H-2 gases. Furthermore, the solid solutions containing Zn(II)/Cd(II) have shown better uptake capacities of gas than parent CPs. These results give some insights into the role of metal ions and anions for fine-tuning the porosity of CPs.

引用

页码：670 / 672

页数：3

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