Modular Design of Domain Assembly in Porous Coordination Polymer Crystals via Reactivity-Directed Crystallization Process

被引：103

作者：

Fukushima, Tomohiro ^{[1
]}

Horike, Satoshi ^{[1
,2
]}

Kobayashi, Hirokazu ^{[3
]}

Tsujimoto, Masahiko ^{[3
]}

Isoda, Seiji ^{[3
]}

Foo, Maw Lin ^{[3
,4
]}

Kubota, Yoshiki ^{[5
]}

Takata, Masaki ^{[6
]}

Kitagawa, Susumu ^{[1
,3
,4
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan

[3] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Sakyo Ku, Kyoto 6068501, Japan

[4] Japan Sci & Technol Agcy, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

[5] Osaka Prefecture Univ, Grad Sch Sci, Dept Phys Sci, Osaka 5998531, Japan

[6] RIKEN SPring 8 Ctr, Sayo, Hyogo 6795198, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 32期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

ADSORPTION; FRAMEWORKS; SIZE; NANOPARTICLES; NANOCRYSTALS; TRANSITIONS; NUCLEATION; SORPTION; STORAGE; PORES;

D O I：

10.1021/ja303588m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mesoscale design of domain assembly is crucial for controlling the bulk properties of solids. Herein, we propose a modular design of domain assembly in porous coordination polymer crystals via exquisite control of the kinetics of the crystal formation process. Employing precursors of comparable chemical reactivity affords the preparation of homogeneous solid-solution type crystals. Employing precursors of distinct chemical reactivity affords the preparation of heterogeneous phase separated crystals. We have utilized this reactivity-directed crystallization process for the facile synthesis of mesoscale architecture which are either solid-solution or phase-separated type crystals. This approach can be also adapted to ternary phase-separated type crystals from one-pot reaction. Phase-separated type frameworks possess unique gas adsorption properties that are not observed in single-phasic compounds. The results shed light on the importance of crystal formation kinetics for control of mesoscale domains in order to create porous solids with unique cooperative functionality.

引用

页码：13341 / 13347

页数：7

共 69 条

[1] Length scale of cooperativity in the dynamic glass transition [J].

Arndt, M ;

Stannarius, R ;

Groothues, H ;

Hempel, E ;

Kremer, F .

PHYSICAL REVIEW LETTERS, 1997, 79 (11) :2077-2080

[2] Mixed-component metal-organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications [J].

Burrows, Andrew D. .

CRYSTENGCOMM, 2011, 13 (11) :3623-3642

[3]

Chmiola J, 2006, SCIENCE, V313, P1760, DOI 10.1126/science/1132195

[4] Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials [J].

Chun, H ;

Dybtsev, DN ;

Kim, H ;

Kim, K .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) :3521-3529

[5] Thermodynamics of Guest-induced Structural Transitions in Hybrid Organic-Inorganic Frameworks [J].

Coudert, Francois-Xavier ;

Jeffroy, Marie ;

Fuchs, Alain H. ;

Boutin, Anne ;

Mellot-Draznieks, Caroline .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (43) :14294-14302

[6] Thermodynamic Methods and Models to Study Flexible Metal-Organic Frameworks [J].

Coudert, Francois-Xavier ;

Boutin, Anne ;

Jeffroy, Marie ;

Mellot-Draznieks, Caroline ;

Fuchs, Alain H. .

CHEMPHYSCHEM, 2011, 12 (02) :247-258

[7] Fast Nucleation and Growth of ZIF-8 Nanocrystals Monitored by Time-Resolved In Situ Small-Angle and Wide-Angle X-Ray Scattering [J].

Cravillon, Janosch ;

Schroeder, Christian A. ;

Nayuk, Roman ;

Gummel, Jeremie ;

Huber, Klaus ;

Wiebcke, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (35) :8067-8071

[8] Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering [J].

Cravillon, Janosch ;

Nayuk, Roman ;

Springer, Sergej ;

Feldhoff, Armin ;

Huber, Klaus ;

Wiebcke, Michael .

CHEMISTRY OF MATERIALS, 2011, 23 (08) :2130-2141

[9] Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal-Organic Frameworks [J].

Das, Sunirban ;

Kim, Hyunuk ;

Kim, Kimoon .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3814-+

[10] Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks [J].

Deng, Hexiang ;

Doonan, Christian J. ;

Furukawa, Hiroyasu ;

Ferreira, Ricardo B. ;

Towne, John ;

Knobler, Carolyn B. ;

Wang, Bo ;

Yaghi, Omar M. .

SCIENCE, 2010, 327 (5967) :846-850

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