Modular Design of Domain Assembly in Porous Coordination Polymer Crystals via Reactivity-Directed Crystallization Process

被引：103

作者：

Fukushima, Tomohiro ^{[1
]}

Horike, Satoshi ^{[1
,2
]}

Kobayashi, Hirokazu ^{[3
]}

Tsujimoto, Masahiko ^{[3
]}

Isoda, Seiji ^{[3
]}

Foo, Maw Lin ^{[3
,4
]}

Kubota, Yoshiki ^{[5
]}

Takata, Masaki ^{[6
]}

Kitagawa, Susumu ^{[1
,3
,4
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan

[3] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Sakyo Ku, Kyoto 6068501, Japan

[4] Japan Sci & Technol Agcy, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

[5] Osaka Prefecture Univ, Grad Sch Sci, Dept Phys Sci, Osaka 5998531, Japan

[6] RIKEN SPring 8 Ctr, Sayo, Hyogo 6795198, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 32期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

ADSORPTION; FRAMEWORKS; SIZE; NANOPARTICLES; NANOCRYSTALS; TRANSITIONS; NUCLEATION; SORPTION; STORAGE; PORES;

D O I：

10.1021/ja303588m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mesoscale design of domain assembly is crucial for controlling the bulk properties of solids. Herein, we propose a modular design of domain assembly in porous coordination polymer crystals via exquisite control of the kinetics of the crystal formation process. Employing precursors of comparable chemical reactivity affords the preparation of homogeneous solid-solution type crystals. Employing precursors of distinct chemical reactivity affords the preparation of heterogeneous phase separated crystals. We have utilized this reactivity-directed crystallization process for the facile synthesis of mesoscale architecture which are either solid-solution or phase-separated type crystals. This approach can be also adapted to ternary phase-separated type crystals from one-pot reaction. Phase-separated type frameworks possess unique gas adsorption properties that are not observed in single-phasic compounds. The results shed light on the importance of crystal formation kinetics for control of mesoscale domains in order to create porous solids with unique cooperative functionality.

引用

页码：13341 / 13347

页数：7

共 69 条

[51] An Adaptable Peptide-Based Porous Material [J].

Rabone, J. ;

Yue, Y. -F. ;

Chong, S. Y. ;

Stylianou, K. C. ;

Bacsa, J. ;

Bradshaw, D. ;

Darling, G. R. ;

Berry, N. G. ;

Khimyak, Y. Z. ;

Ganin, A. Y. ;

Wiper, P. ;

Claridge, J. B. ;

Rosseinsky, M. J. .

SCIENCE, 2010, 329 (5995) :1053-1057

[52] A net-based approach to coordination polymers [J].

Robson, R .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3735-3744

[53]

Sato H, 2010, NAT MATER, V9, P661, DOI [10.1038/NMAT2808, 10.1038/nmat2808]

[54] Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites [J].

Stock, Norbert ;

Biswas, Shyam .

CHEMICAL REVIEWS, 2012, 112 (02) :933-969

[55] Control of the charge-transfer interaction between a flexible porous coordination host and aromatic guests by framework isomerism [J].

Takashima, Yohei ;

Furukawa, Shuhei ;

Kitagawa, Susumu .

CRYSTENGCOMM, 2011, 13 (10) :3360-3363

[56] Postsynthetic modification of metal-organic frameworks-a progress report [J].

Tanabe, Kristine K. ;

Cohen, Seth M. .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (02) :498-519

[57] Kinetic gate-opening process in a flexible porous coordination polymer [J].

Tanaka, Daisuke ;

Nakagawa, Keiji ;

Higuchi, Masakazu ;

Horike, Satoshi ;

Kubota, Yoshiki ;

Kobayashi, Latsuo C. ;

Takata, Masaki ;

Kitagawa, Susumu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (21) :3914-3918

[58]

Tanaka D, 2010, NAT CHEM, V2, P410, DOI [10.1038/NCHEM.627, 10.1038/nchem.627]

[59] POLYMER-PROTECTED PALLADIUM-PLATINUM BIMETALLIC CLUSTERS - PREPARATION, CATALYTIC PROPERTIES AND STRUCTURAL CONSIDERATIONS [J].

TOSHIMA, N ;

YONEZAWA, T ;

KUSHIHASHI, K .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (14) :2537-2543

[60] Mechanism of Breathing Transitions in Metal-Organic Frameworks [J].

Triguero, Carles ;

Coudert, Francois-Xavier ;

Boutin, Anne ;

Fuchs, Alain H. ;

Neimark, Alexander V. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2011, 2 (16) :2033-2037

← 1 2 3 4 5 6 7 →