A net-based approach to coordination polymers

被引：783

作者：

Robson, R ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 21期

关键词：

D O I：

10.1039/b003591m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

True crystal engineering of coordination polymers with useful structure-based properties by design remains a distant prospect. The exploratory, experimental net-based approach to the construction of coordination polymers described in this article has provided a few examples of structures obtained by design, but also serendipitously revealed numbers of unprecedented and interesting structures that were totally unexpected. Further work with coordination polymers can confidently be expected to provide many similar surprises. It is proposed that carefully designed connecting ligands capable of binding metal centres strongly and predictably at chelating sites may afford improved structural control in network assembly and more robust network structures.

引用

页码：3735 / 3744

页数：10

共 31 条

[1] X-Ray diffraction and magnetic studies on a series of isostructural divalent metal chloranilates with zigzag polymeric chain structures and on a dinuclear iron(III) chloranilate [J].

Abrahams, BF ;

Lu, KD ;

Moubaraki, B ;

Murray, KS ;

Robson, R .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (11) :1793-1797

[2] A Wellsian 'three-dimensional' racemate: Eight interpenetrating, enantiomorphic (10,3)-a nets, four right- and four left-handed [J].

Abrahams, BF ;

Batten, SR ;

Hamit, H ;

Hoskins, BF ;

Robson, R .

CHEMICAL COMMUNICATIONS, 1996, (11) :1313-1314

[3]

Abrahams BF, 1999, ANGEW CHEM INT EDIT, V38, P1475, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1475::AID-ANIE1475>3.0.CO

[4]

2-3

[5] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

MICHAIL, DM ;

ROBSON, R .

NATURE, 1994, 369 (6483) :727-729

[6] A HONEYCOMB FORM OF CADMIUM CYANIDE - A NEW TYPE OF 3-D ARRANGEMENT OF INTERCONNECTED RODS GENERATING INFINITE LINEAR CHANNELS OF LARGE HEXAGONAL CROSS-SECTION [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (01) :60-61

[7] Gas hydrate-like pentagonal dodecahedral M(2)(H2O)(18) cages (M equals lanthanide or Y) in 2,5-dihydroxybenzoquinone-derived coordination polymers [J].

Abrahams, BF ;

Coleiro, J ;

Hoskins, BF ;

Robson, R .

CHEMICAL COMMUNICATIONS, 1996, (05) :603-604

[8] A cubic (3,4)-connected net with large cavities in solvated [Cu-3(tpt)(4)](ClO4)(3) (tpt=2,4,6-tri(4-pyridyl)-1,3,5-triazine) [J].

Abrahams, BF ;

Batten, SR ;

Hamit, H ;

Hoskins, BF ;

Robson, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (15) :1690-1692

[9]

Abrahams BF, 1998, ANGEW CHEM INT EDIT, V37, P2656, DOI 10.1002/(SICI)1521-3773(19981016)37:19<2656::AID-ANIE2656>3.0.CO

[10]

2-M

← 1 2 3 4 →