Control of the charge-transfer interaction between a flexible porous coordination host and aromatic guests by framework isomerism

被引：46

作者：

Takashima, Yohei ^{[1
,2
]}

Furukawa, Shuhei ^{[1
,3
]}

Kitagawa, Susumu ^{[1
,2
,3
]}

机构：

[1] Japan Sci & Technol Agcy JST, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

[2] Kyoto Univ, Dept Synthet Chem & Biol Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

[3] Kyoto Univ, Inst Integrated Cell Mat Sci, Sakyo Ku, Kyoto 6068501, Japan

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 10期

关键词：

METAL-ORGANIC FRAMEWORKS; CATENATION ISOMERISM; MOLECULES; POLYMERS; SORPTION; STORAGE; TEMPERATURE; CHIRALITY; NETWORK; DESIGN;

D O I：

10.1039/c1ce05201b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on 2,5-thiophenedicarboxylate (thdc), two isomorphic frameworks, [Zn(thdc)(dpNDI)](n), are assembled from zinc ions and N, N'-di(4-pyridyl)-1,4,5,8-naphthalenediimide (dpNDI). Because of the significant difference in their porous structures, these isomers show different charge-transfer interactions with electron-donating aromatic molecules.

引用

收藏

页码：3360 / 3363

页数：4

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