Design, chirality, and flexibility in nanoporous molecule-based materials

被引：1202

作者：

Bradshaw, D ^{[1
]}

Claridge, JB ^{[1
]}

Cussen, EJ ^{[1
]}

Prior, TJ ^{[1
]}

Rosseinsky, MJ ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2005年 / 38卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ar0401606

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Scientific and technological interest in porous materials with molecule-sized channels and cavities has led to an intense search for controlled chemical routes to systems with specific properties. This Account details our work on directing the assembly of open-framework structures based on molecules and investigating how the response of nanoporous examples of such materials to guests differs from classical rigid porous systems. The stabilization of chiral nanoporosity by a hierarchy of interactions that both direct and maintain a helical open-framework structure exemplifies the approach.

引用

页码：273 / 282

页数：10

共 38 条

[1] Zinc saccharate: A robust, 3D coordination network with two types of isolated, parallel channels, one hydrophilic and the other hydrophobic [J].

Abrahams, BF ;

Moylan, M ;

Orchard, SD ;

Robson, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (16) :1848-1851

[2] [Ni2O(L-Asp)(H2O)2]•4H2O:: A homochiral 1D helical chain hybrid compound with extended Ni-O-Ni bonding [J].

Anokhina, EV ;

Jacobson, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) :3044-3045

[3] Permanent microporosity and enantioselective sorption in a chiral open framework [J].

Bradshaw, D ;

Prior, TJ ;

Cussen, EJ ;

Claridge, JB ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114

[4]

Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO

[5]

2-U

[6] Flexible sorption and transformation behavior in a microporous metal-organic framework [J].

Cussen, EJ ;

Claridge, JB ;

Rosseinsky, MJ ;

Kepert, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (32) :9574-9581

[7] ZEOLITE AND MOLECULAR-SIEVE SYNTHESIS [J].

DAVIS, ME ;

LOBO, RF .

CHEMISTRY OF MATERIALS, 1992, 4 (04) :756-768

[8] Ordered porous materials for emerging applications [J].

Davis, ME .

NATURE, 2002, 417 (6891) :813-821

[9] Adsorption of gases and vapors on nanoporous Ni2(4,4′-bipyridine)3(NO3)4 metal-organic framework materials templated with methanol and ethanol:: Structural effects in adsorption kinetics [J].

Fletcher, AJ ;

Cussen, EJ ;

Bradshaw, D ;

Rosseinsky, MJ ;

Thomas, KM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (31) :9750-9759

[10] Adsorption dynamics of gases and vapors on the nanoporous metal organic framework material Ni2(4,4′-bipyridine)3(NO3)4:: Guest modification of host sorption behavior [J].

Fletcher, AJ ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ ;

Kepert, CJ ;

Thomas, KM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (41) :10001-10011

← 1 2 3 4 →