[Ni2O(L-Asp)(H2O)2]•4H2O:: A homochiral 1D helical chain hybrid compound with extended Ni-O-Ni bonding

被引：184

作者：

Anokhina, EV ^{[1
]}

Jacobson, AJ ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 10期

关键词：

D O I：

10.1021/ja031836f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrothermally synthesized 1D homochiral nickel aspartate oxide [Ni2O(l-Asp)(H2O)2]·4H2O is based on infinite helical chains of edge- and corner-sharing nickel octahedra. It represents the first example of a chiral one-dimensional compound with an extended helical TM?O?TM subnetwork synthesized as an optically pure product. Its structure was determined ab initio by real-space methods from laboratory powder diffraction data. Copyright © 2004 American Chemical Society.

引用

页码：3044 / 3045

页数：2

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