Solid Solutions of Soft Porous Coordination Polymers: Fine-Tuning of Gas Adsorption Properties

被引：272

作者：

Fukushima, Tomohiro ^{[1
]}

Horike, Satoshi ^{[1
]}

Inubushi, Yasutaka

Nakagawa, Keiji ^{[1
]}

Kubota, Yoshiki ^{[4
]}

Takata, Masaki ^{[5
]}

Kitagawa, Susumu ^{[1
,2
,3
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

[2] Sci & Technol Agcy JST, Inst Integrated Cell Mat Sci, Tokyo, Japan

[3] Sci & Technol Agcy JST, Kitagawa Integrated Pore Project, Exploratory Res Adv Technol ERATO, Tokyo, Japan

[4] Osaka Prefecture Univ, Osaka, Japan

[5] Japan Synchrotron Radiat Res Inst SPring 8, Hyogo 6795198, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 28期

关键词：

adsorption; carbon dioxide; coordination polymers; gas separation; water; METAL-ORGANIC FRAMEWORK; HIGH-SURFACE-AREA; SORPTION PROPERTIES; HYDROGEN STORAGE; MOLECULES; ZEOLITE; FLEXIBILITY; INCLUSION; CRYSTALS; POROSITY;

D O I：

10.1002/anie.201000989

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) My flexible friend: Separation of a CO2/ CH4 mixture was optimized by varying the composition of solid solutions of interdigitated 2D frameworks comprising two different isophthalate ligands (see picture). The characteristics of the solid solutions were dependent on the ligand ratio, which influenced the inherent flexibility and therefore the adsorption properties of the frameworks. © 2010 Wlley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4820 / 4824

页数：5

共 31 条

[1] A route to high surface area, porosity and inclusion of large molecules in crystals [J].

Chae, HK ;

Siberio-Pérez, DY ;

Kim, J ;

Go, Y ;

Eddaoudi, M ;

Matzger, AJ ;

O'Keeffe, M ;

Yaghi, OM .

NATURE, 2004, 427 (6974) :523-527

[2] Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules [J].

Chen, Banglin ;

Ma, Shengqian ;

Zapata, Fatima ;

Fronczek, Frank R. ;

Lobkovsky, Emil B. ;

Zhou, Hong-Cai .

INORGANIC CHEMISTRY, 2007, 46 (04) :1233-1236

[3] A microporous metal-organic framework for gas-chromatographic separation of alkanes [J].

Chen, BL ;

Liang, CD ;

Yang, J ;

Contreras, DS ;

Clancy, YL ;

Lobkovsky, EB ;

Yaghi, OM ;

Dai, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1390-1393

[4]

CHEN BL, 2006, ANGEW CHEM INT ED, V0118

[5] Broadly hysteretic H2 adsorption in the microporous metal-organic framework Co(1,4-benzenedipyrazolate) [J].

Choi, Hye Jin ;

Dinca, Mircea ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (25) :7848-+

[6] Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials [J].

Chun, H ;

Dybtsev, DN ;

Kim, H ;

Kim, K .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) :3521-3529

[7] A zeolite with interconnected 8-, 10- and 12-ring pores and its unique catalytic selectivity [J].

Corma, A ;

Rey, F ;

Valencia, S ;

Jordá, JL ;

Rius, J .

NATURE MATERIALS, 2003, 2 (07) :493-497

[8] Thermodynamics of Guest-induced Structural Transitions in Hybrid Organic-Inorganic Frameworks [J].

Coudert, Francois-Xavier ;

Jeffroy, Marie ;

Fuchs, Alain H. ;

Boutin, Anne ;

Mellot-Draznieks, Caroline .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (43) :14294-14302

[9] Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks [J].

Deng, Hexiang ;

Doonan, Christian J. ;

Furukawa, Hiroyasu ;

Ferreira, Ricardo B. ;

Towne, John ;

Knobler, Carolyn B. ;

Wang, Bo ;

Yaghi, Omar M. .

SCIENCE, 2010, 327 (5967) :846-850

[10] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

← 1 2 3 4 →