Postsynthetic modification of metal-organic frameworks-a progress report

被引：1032

作者：

Tanabe, Kristine K. ^{[1
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2011年 / 40卷 / 02期

基金：

美国国家科学基金会;

关键词：

HYDROGEN SORPTION PROPERTIES; FUNCTIONAL-GROUPS; PORE-SIZE; COVALENT MODIFICATION; POROUS SOLIDS; STORAGE; BINDING; REACTIVITY; PROTECTION; CATALYSIS;

D O I：

10.1039/c0cs00031k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs) are an important class of hybrid inorganic-organic materials. In this tutorial review, a progress report on the postsynthetic modification (PSM) of MOFs is provided. PSM refers to the chemical modification of the MOF lattice in a heterogeneous fashion. This powerful synthetic approach has grown in popularity and resulted in a number of advances in the functionalization and application of MOFs. The use of PSM to develop MOFs with improved gas sorption, catalytic activity, bioactivity, and more robust physical properties is discussed. The results reported to date clearly show that PSM is an important approach for the development and advancement of these hybrid solids.

引用

页码：498 / 519

页数：22

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