Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification

被引：376

作者：

Bae, Youn-Sang ^{[2
]}

Farha, Omar K. ^{[1
]}

Hupp, Joseph T. ^{[1
]}

Snurr, Randall Q. ^{[2
]}

机构：

[1] Northwestern Univ, Dept Chem & Int Inst Nanotechnol, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2009年 / 19卷 / 15期

关键词：

MOLECULAR SIMULATION; ACTIVATED CARBON; HYDROGEN UPTAKE; ADSORPTION; CO2; SEPARATION; GASES; CH4; ELABORATION; CATALYSIS;

D O I：

10.1039/b900390h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Post-synthesis modification of a MOF by replacing coordinated solvent molecules with highly polar ligands leads to considerable enhancement of CO2/N-2 selectivity.

引用

页码：2131 / 2134

页数：4

共 40 条

[1]

Storage and separation of CO2 and CH4 in silicalite, C168 schwarzite, and IRMOF-1:: A comparative study from monte carlo simulation [J].

Babarao, Ravichandar ;

Hu, Zhongqiao ;

Jiang, Jianwen ;

Chempath, Shaji ;

Sandler, Stanley I. .

LANGMUIR, 2007, 23 (02) :659-666

[2]

Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks [J].

Bae, Youn-Sang ;

Mulfort, Karen L. ;

Frost, Houston ;

Ryan, Patrick ;

Punnathanam, Sudeep ;

Broadbelt, Linda J. ;

Hupp, Joseph T. ;

Snurr, Randall Q. .

LANGMUIR, 2008, 24 (16) :8592-8598

[3]

Sorption kinetics of eight gases on a carbon molecular sieve at elevated pressure [J].

Bae, YS ;

Lee, CH .

CARBON, 2005, 43 (01) :95-107

[4]

A microporous metal-organic framework for separation of CO2/N2 and CO2/CH4 by fixed-bed adsorption [J].

Bastin, Laurent ;

Barcia, Patrick S. ;

Hurtado, Eric J. ;

Silva, Jose A. C. ;

Rodrigues, Alirio E. ;

Chen, Banglin .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (05) :1575-1581

[5]

Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47 [J].

Bourrelly, S ;

Llewellyn, PL ;

Serre, C ;

Millange, F ;

Loiseau, T ;

Férey, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) :13519-13521

[6]

Adsorption and separation of hydrogen isotopes in carbon nanotubes: Multicomponent grand canonical Monte Carlo simulations [J].

Challa, SR ;

Sholl, DS ;

Johnson, JK .

JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (02) :814-824

[7]

A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[8]

High pressure adsorption data of methane, nitrogen, carbon dioxide and their binary and ternary mixtures on activated carbon [J].

Dreisbach, F ;

Staudt, R ;

Keller, JU .

ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 1999, 5 (03) :215-227

[9]

Calculating geometric surface areas as a characterization tool for metal-organic frameworks [J].

Dueren, Tina ;

Millange, Franck ;

Ferey, Gerard ;

Walton, Krista S. ;

Snurr, Randall Q. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (42) :15350-15356

[10]

Assessment of isoreticular metal-organic frameworks for adsorption separations:: A molecular simulation study of methane/n-butane mixtures [J].

Düren, T ;

Snurr, RQ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (40) :15703-15708

← 1 2 3 4 →