Sulfur-tagged metal-organic frameworks and their post-synthetic oxidation

被引：87

作者：

Burrows, Andrew D. ^{[1
]}

Frost, Christopher G. ^{[1
]}

Mahon, Mary F. ^{[1
]}

Richardson, Christopher ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 28期

基金：

英国工程与自然科学研究理事会;

关键词：

POSTSYNTHETIC COVALENT MODIFICATION; COORDINATION POLYMERS; PORE-SIZE; FUNCTIONALIZATION; REACTIVITY; DESIGN; MOFS;

D O I：

10.1039/b906170c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of sulfur-tagged zinc MOFs containing functionalised 4,4'-biphenyldicarboxylate ligands has been prepared: oxidative post-synthetic modification with dimethyldioxirane has converted the sulfide tags into sulfones, leaving the MOF networks intact.

引用

收藏

页码：4218 / 4220

页数：3

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