Covalent surface modification of a metal-organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition

被引:137
作者
Gadzikwa, Tendai [2 ,3 ]
Lu, Guang [2 ,3 ]
Stern, Charlotte L. [2 ,3 ]
Wilson, Scott R. [1 ]
Hupp, Joseph T. [2 ,3 ]
Nguyen, SonBinh T. [2 ,3 ]
机构
[1] Univ Illinois, Sch Chem Sci, Mat Chem Lab, Urbana, IL 61801 USA
[2] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[3] Northwestern Univ, Inst Catalysis Energy Proc, Evanston, IL 60208 USA
关键词
D O I
10.1039/b805101a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via 'click chemistry', in a demonstration of selective post-synthesis functionalization.
引用
收藏
页码:5493 / 5495
页数:3
相关论文
共 26 条
[1]  
Bélanger S, 1999, ELEC SOC S, V98, P208
[2]   Hydrogen adsorption in an interpenetrated dynamic metal-organic framework [J].
Chen, Banglin ;
Ma, Shengqian ;
Zapata, Fatima ;
Lobkovsky, Emil B. ;
Yang, Jun .
INORGANIC CHEMISTRY, 2006, 45 (15) :5718-5720
[3]   A microporous metal-organic framework for gas-chromatographic separation of alkanes [J].
Chen, BL ;
Liang, CD ;
Yang, J ;
Contreras, DS ;
Clancy, YL ;
Lobkovsky, EB ;
Yaghi, OM ;
Dai, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1390-1393
[4]  
Cho S., 2007, PMSE PREPR, V97, P95
[5]   A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation [J].
Cho, So-Hye ;
Ma, Baoqing ;
Nguyen, SonBinh T. ;
Hupp, Joseph T. ;
Albrecht-Schmitt, Thomas E. .
CHEMICAL COMMUNICATIONS, 2006, (24) :2563-2565
[6]   Hydrogen storage in metal-organic frameworks [J].
Collins, David J. ;
Zhou, Hong-Cai .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) :3154-3160
[7]   Chemical modification of a bridging ligand inside a metal-organic framework while maintaining the 3D structure [J].
Costa, Jose Sanchez ;
Gamez, Patrick ;
Black, Cory A. ;
Roubeau, Olivier ;
Teat, Simon J. ;
Reedijk, Jan .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (10) :1551-1554
[8]   High-enthalpy hydrogen adsorption in cation-exchanged variants of the microporous metal-organic framework Mn3[(Mn4Cl)3(BTT)8(CH3OH)10]2 [J].
Dinca, Mircea ;
Long, Jeffrey R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (36) :11172-11176
[9]   Design of new materials for methane storage [J].
Düren, T ;
Sarkisov, L ;
Yaghi, OM ;
Snurr, RQ .
LANGMUIR, 2004, 20 (07) :2683-2689
[10]   Ligand-elaboration as a strategy for engendering structural diversity in porous metal-organic framework compounds [J].
Gadzikwa, Tendai ;
Zeng, Bi-Shun ;
Hupp, Joseph T. ;
Nguyen, SonBinh T. .
CHEMICAL COMMUNICATIONS, 2008, (31) :3672-3674