A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation

被引：928

作者：

Cho, So-Hye

Ma, Baoqing

Nguyen, SonBinh T.

Hupp, Joseph T.

Albrecht-Schmitt, Thomas E.

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Inst Environm Catalysis, Evanston, IL 60208 USA

[3] Auburn Univ, Dept Chem & Biochem, Auburn, AL 36830 USA

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 24期

关键词：

D O I：

10.1039/b600408c

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

A new microporous metal - organic framework compound featuring chiral ( salen) Mn struts is highly effective as an asymmetric catalyst for olefin epoxidation, yielding enantiomeric excesses that rival those of the free molecular analogue. Framework confinement of the manganese salen entity enhances catalyst stability, imparts substrate size selectivity, and permits catalyst separation and reuse.

引用

页码：2563 / 2565

页数：3

共 22 条

[1]

Biradha K, 1999, ANGEW CHEM INT EDIT, V38, P492, DOI 10.1002/(SICI)1521-3773(19990215)38:4<492::AID-ANIE492>3.0.CO

[2]

2-#

[3]

Design, chirality, and flexibility in nanoporous molecule-based materials [J].