Recent progress towards the understanding of metal-salen catalysed asymmetric alkene epoxidation

被引：159

作者：

Dalton, CT ^{[1
]}

Ryan, KM ^{[1
]}

Wall, VM ^{[1
]}

Bousquet, C ^{[1
]}

Gilheany, DG ^{[1
]}

机构：

[1] Univ Coll Dublin, Dept Chem, Dublin 4, Ireland

来源：

TOPICS IN CATALYSIS | 1998年 / 5卷 / 1-4期

关键词：

catalytic asymmetric epoxidation; metal-salen complexes; salicylaldimines; alkene epoxidation; chromium-salen complexes; metallaoxetanes; 2+2] cycloaddition;

D O I：

10.1023/A:1019102003494

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The history of the development of useful catalyst systems for the asymmetric epoxidation of alkenes is described. An overview is presented of the present state of understanding of the mechanism of the most successful catalysts to date, metal-salen complexes. Recent results from the chromium-salen series are presented and their implications for the mechanism are discussed.

引用

页码：75 / 91

页数：17

共 116 条

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