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Recent progress towards the understanding of metal-salen catalysed asymmetric alkene epoxidation

被引：159
作者：
Dalton, CT [1 ]
Ryan, KM [1 ]
Wall, VM [1 ]
Bousquet, C [1 ]
Gilheany, DG [1 ]
机构：
[1] Univ Coll Dublin, Dept Chem, Dublin 4, Ireland
来源：
TOPICS IN CATALYSIS | 1998年 / 5卷 / 1-4期
关键词：
catalytic asymmetric epoxidation; metal-salen complexes; salicylaldimines; alkene epoxidation; chromium-salen complexes; metallaoxetanes; 2+2] cycloaddition;
D O I：
10.1023/A:1019102003494
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The history of the development of useful catalyst systems for the asymmetric epoxidation of alkenes is described. An overview is presented of the present state of understanding of the mechanism of the most successful catalysts to date, metal-salen complexes. Recent results from the chromium-salen series are presented and their implications for the mechanism are discussed.
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收藏
页码：75 / 91
页数：17
相关论文
共 116 条
  • [91] Rees, 1984, COMPREHENSIVE HETERO, V7, P95
  • [92] Aerobic epoxidation via alkyl-2-oxocyclopentanecarboxylate co-oxidation with cobalt or manganese Jacobsen-type catalysts
    Rhodes, B
    Rowling, S
    Tidswell, P
    Woodward, S
    Brown, SM
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 116 (03) : 375 - 384
  • [93] OXIDATION OF ALKYNES AND YLIDES BY OXO(SALEN)CHROMIUM(V) (SALEN = N,N'-ETHYLENEBIS-SALICYLIDENEIMINATO) TRIFLUOROMETHANESULPHONATE
    RIHTER, B
    MASNOVI, J
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (01) : 35 - 37
  • [94] REACTIONS OF ALKYNES AND CARBENE EQUIVALENTS WITH OXO(SALEN)CHROMIUM(V) COMPLEXES
    RIHTER, B
    SRIHARI, S
    HUNTER, S
    MASNOVI, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (10) : 3918 - 3924
  • [95] RISPENS MT, 1994, RECL TRAV CHIM PAY B, V113, P413
  • [96] BROMINATED AND CHLORINATED MANGANESE CHIRAL SCHIFF-BASE COMPLEXES AS EPOXIDATION CATALYSTS
    ROBERT, A
    TSAPARA, A
    MEUNIER, B
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1993, 85 (01): : 13 - 19
  • [97] MECHANISM OF THE CHROMIUM-CATALYZED EPOXIDATION OF OLEFINS - ROLE OF OXOCHROMIUM(V) CATIONS
    SAMSEL, EG
    SRINIVASAN, K
    KOCHI, JK
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (25) : 7606 - 7617
  • [98] A BIOMIMETIC CATALYST FOR THE ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS WITH HYDROGEN-PEROXIDE
    SCHWENKREIS, T
    BERKESSEL, A
    [J]. TETRAHEDRON LETTERS, 1993, 34 (30) : 4785 - 4788
  • [99] The role of 4-(3-phenylpropyl)pyridine N-oxide (P3NO) in the manganese-salen-catalyzed asymmetric epoxidation of indene
    Senanayake, CH
    Smith, GB
    Ryan, KM
    Fredenburgh, LE
    Liu, J
    Roberts, FE
    Hughes, DL
    Larsen, RD
    Verhoeven, TR
    Reider, PJ
    [J]. TETRAHEDRON LETTERS, 1996, 37 (19) : 3271 - 3274
  • [100] CHROMYL CHLORIDE OXIDATIONS OF OLEFINS - POSSIBLE ROLE OF ORGANOMETALLIC INTERMEDIATES IN OXIDATIONS OF OLEFINS BY OXO TRANSITION-METAL SPECIES
    SHARPLESS, KB
    TERANISHI, AY
    BACKVALL, JE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (09) : 3120 - 3128
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