Recent progress towards the understanding of metal-salen catalysed asymmetric alkene epoxidation

被引：159

作者：

Dalton, CT ^{[1
]}

Ryan, KM ^{[1
]}

Wall, VM ^{[1
]}

Bousquet, C ^{[1
]}

Gilheany, DG ^{[1
]}

机构：

[1] Univ Coll Dublin, Dept Chem, Dublin 4, Ireland

来源：

TOPICS IN CATALYSIS | 1998年 / 5卷 / 1-4期

关键词：

catalytic asymmetric epoxidation; metal-salen complexes; salicylaldimines; alkene epoxidation; chromium-salen complexes; metallaoxetanes; 2+2] cycloaddition;

D O I：

10.1023/A:1019102003494

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The history of the development of useful catalyst systems for the asymmetric epoxidation of alkenes is described. An overview is presented of the present state of understanding of the mechanism of the most successful catalysts to date, metal-salen complexes. Recent results from the chromium-salen series are presented and their implications for the mechanism are discussed.

引用

页码：75 / 91

页数：17

共 116 条

[61] SYNTHESIS OF MN-SALEN CATALYST BEARING (1R,2R,3R,6R)-3,6-DIMETHYLCYCLOHEXANE-1,2-DIAMINE AS AN ETHYLENEDIAMINE PART AND ITS APPLICATION TO ASYMMETRIC EPOXIDATION
KUROKI, T
HAMADA, T
KATSUKI, T
[J]. CHEMISTRY LETTERS, 1995, (05) : 339 - 340
[62] Is there a radical intermediate in the (salen)Mn-catalyzed epoxidation of alkenes?
Linde, C
Arnold, M
Norrby, PO
Akermark, B
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (16): : 1723 - 1725
[63] The Jacobsen-Katsuki epoxidation and its controversial mechanism
Linker, T
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (19): : 2060 - 2062
[64] LYNCH CM, 1955, J CHEM SOC, P1525
[65] ASYMMETRIC-SYNTHESIS - ASYMMETRIC CATALYTIC-HYDROGENATION USING CHIRAL CHELATING 6-MEMBERED RING DIPHOSPHINES
MACNEIL, PA
ROBERTS, NK
BOSNICH, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (09) : 2273 - 2280
[66] Manganese(II)complexes of 3,6,9-trioxaundecanedioic acid (3,6,9-tddaH(2)): X-ray crystal structures of [Mn(3,6,9-tdda)(H2O)(2)]center dot 2H(2)O and {[Mn(3,6,9-tdda)(phen)(2)center dot 3H(2)O]center dot EtOH}(n)
McCann, S
McCann, M
Casey, MT
Devereux, M
McKee, V
McMichael, P
McCrea, JG
[J]. POLYHEDRON, 1997, 16 (24) : 4247 - 4252
[67] MCKEE V, COMMUNICATION
[68] METCALFE T, 1998, THESIS QUB
[69] SODIUM-HYPOCHLORITE - A CONVENIENT OXYGEN SOURCE FOR OLEFIN EPOXIDATION CATALYZED BY (PORPHYRINATO)MANGANESE COMPLEXES
MEUNIER, B
GUILMET, E
DECARVALHO, ME
POILBLANC, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (22) : 6668 - 6676
[70] MIKAME D, 1995, SYNLETT, P827

← 2 3 4 5 6 7 8 9 10 11 →