Post-Synthetic Modification of Tagged Metal-Organic Frameworks

被引：276

作者：

Burrows, Andrew D. ^{[1
]}

Frost, Christopher G. ^{[1
]}

Mahon, Mary F. ^{[1
]}

Richardson, Christopher ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 44期

关键词：

metal-organic frameworks; microporous materials; post-synthetic modification; X-ray diffraction; zinc;

D O I：

10.1002/anie.200802908

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

(Chemical Equation Presented) Playing tag with MOFs: Zinc metal-organic frameworks with pendant aldehyde and methoxy groups are prepared. The aldehyde-tagged MOF takes up 2,4-dinitrophenylhydrazine, reacting to form a hydrazone-functionalized MOF which is crystallographically characterized. Use of both aldehyde- and methoxy-functionalized dicarboxylates leads to MOFs containing both ligands, of which the aldehyde groups can be selectively reacted. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：8482 / 8486

页数：5

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