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Selective adsorption and separation of xylene isomers and ethylbenzene with the microporous vanadium(IV) terephthalate MIL-47

被引：562
作者：
Alaerts, Luc
Kirschhock, Christine E. A.
Maes, Michael
van der Veen, Monique A.
Finsy, Vincent
Depla, Anouschka
Martens, Johan A.
Baron, Gino V.
Jacobs, Pierre A.
Denayer, Joeri E. M.
De Vos, Dirk E.
机构：
[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium
[2] Vrije Univ Brussel, Dept Chem Engn, B-1050 Brussels, Belgium
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 23期
关键词：
adsorption; host-guest systems; liquid chromatography; metal-organic frameworks; microporous materials;
D O I：
10.1002/anie.200700056
中图分类号：
O6 [化学];
学科分类号：
0703 [化学];
摘要：
(Figure Presented) A breakthrough result: The microporous metal-organic framework MIL-47 is an excellent adsorbent for the separation of C8 alkylaromatic compounds, such as ethylbenzene, meta-xylene, and para-xylene. The potential of MIL-47, with its high uptake capacity and its hydrophobic nature, for real separations of the C8 alkylaromatic compounds was demonstrated by breakthrough and chromatographic experiments (see picture). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：4293 / 4297
页数：5
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