Clickable Metal-Organic Framework

被引：232

作者：

Goto, Yuta ^{[1
]}

Sato, Hiroki ^{[1
]}

Shinkai, Seiji ^{[1
]}

Sada, Kazuki ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Nishi Ku, Fukuoka 8190395, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 44期

关键词：

D O I：

10.1021/ja7114053

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We demonstrated the metal-organic framework bearing the azide group in the organic linkers and in situ click reactions with some small alkynes. The XRPD patterns indicated that the click reaction proceeded without any decomposition of the original MOF network. Controlling the organic linkers and incorporation of the azide groups should provide the designer-made MOFs that have controlled molecular cavities with the desired steric dimensions and functionality.

引用

页码：14354 / +

页数：3

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