Modular Design of Domain Assembly in Porous Coordination Polymer Crystals via Reactivity-Directed Crystallization Process

被引：103

作者：

Fukushima, Tomohiro ^{[1
]}

Horike, Satoshi ^{[1
,2
]}

Kobayashi, Hirokazu ^{[3
]}

Tsujimoto, Masahiko ^{[3
]}

Isoda, Seiji ^{[3
]}

Foo, Maw Lin ^{[3
,4
]}

Kubota, Yoshiki ^{[5
]}

Takata, Masaki ^{[6
]}

Kitagawa, Susumu ^{[1
,3
,4
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan

[3] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Sakyo Ku, Kyoto 6068501, Japan

[4] Japan Sci & Technol Agcy, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

[5] Osaka Prefecture Univ, Grad Sch Sci, Dept Phys Sci, Osaka 5998531, Japan

[6] RIKEN SPring 8 Ctr, Sayo, Hyogo 6795198, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 32期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

ADSORPTION; FRAMEWORKS; SIZE; NANOPARTICLES; NANOCRYSTALS; TRANSITIONS; NUCLEATION; SORPTION; STORAGE; PORES;

D O I：

10.1021/ja303588m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mesoscale design of domain assembly is crucial for controlling the bulk properties of solids. Herein, we propose a modular design of domain assembly in porous coordination polymer crystals via exquisite control of the kinetics of the crystal formation process. Employing precursors of comparable chemical reactivity affords the preparation of homogeneous solid-solution type crystals. Employing precursors of distinct chemical reactivity affords the preparation of heterogeneous phase separated crystals. We have utilized this reactivity-directed crystallization process for the facile synthesis of mesoscale architecture which are either solid-solution or phase-separated type crystals. This approach can be also adapted to ternary phase-separated type crystals from one-pot reaction. Phase-separated type frameworks possess unique gas adsorption properties that are not observed in single-phasic compounds. The results shed light on the importance of crystal formation kinetics for control of mesoscale domains in order to create porous solids with unique cooperative functionality.

引用

页码：13341 / 13347

页数：7

共 69 条

[41] The middle way [J].

Laughlin, RB ;

Pines, D ;

Schmalian, J ;

Stojkovic, BP ;

Wolynes, P .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2000, 97 (01) :32-37

[42] STATISTICAL THEORY OF EQUATIONS OF STATE AND PHASE TRANSITIONS .2. LATTICE GAS AND ISING MODEL [J].

LEE, TD ;

YANG, CN .

PHYSICAL REVIEW, 1952, 87 (03) :410-419

[43] THERMODYNAMIC CONTROL OF GOLD NANOCRYSTAL SIZE - EXPERIMENT AND THEORY [J].

LEFF, DV ;

OHARA, PC ;

HEATH, JR ;

GELBART, WM .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (18) :7036-7041

[44] Hydrogen bond-regulated microporous nature of copper complex-assembled microcrystals [J].

Li, D ;

Kaneko, K .

CHEMICAL PHYSICS LETTERS, 2001, 335 (1-2) :50-56

[45] The composition-dependent mechanical properties of Ge/Si core-shell nanowires [J].

Liu, X. W. ;

Hu, J. ;

Pan, B. C. .

PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2008, 40 (10) :3042-3048

[46] Effect of mixing of metal cations on the topology of metal oxide networks [J].

Livage, Carine ;

Forster, Paul M. ;

Guillou, Nathalie ;

Tafoya, Maya M. ;

Cheetham, Anthony K. ;

Ferey, Gerard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (31) :5877-5879

[47] Nanoionics: ion transport and electrochemical storage in confined systems [J].

Maier, J .

NATURE MATERIALS, 2005, 4 (11) :805-815

[48] Enhanced selectivity of CO2 from a ternary gas mixture in an interdigitated porous framework [J].

Nakagawa, Keiji ;

Tanaka, Daisuke ;

Horike, Satoshi ;

Shimomura, Satoru ;

Higuchi, Masakazu ;

Kitagawa, Susumu .

CHEMICAL COMMUNICATIONS, 2010, 46 (24) :4258-4260

[49] Modulated Formation of MOF-5 Nanoparticles-A SANS Analysis [J].

Nayuk, R. ;

Zacher, D. ;

Schweins, R. ;

Wiktor, C. ;

Fischer, R. A. ;

van Tendeloo, G. ;

Huber, K. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (10) :6127-6135

[50] Synthesis of "solid solution" and "core-shell" type cobalt-platinum magnetic nanoparticles via transmetalation reactions [J].

Park, JI ;

Cheon, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (24) :5743-5746

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