Magnetic ordering and negative thermal expansion in PrFeAsO

被引:93
作者
Kimber, S. A. J. [1 ]
Argyriou, D. N. [1 ]
Yokaichiya, F. [1 ]
Habicht, K. [1 ]
Gerischer, S. [1 ]
Hansen, T. [2 ]
Chatterji, T. [3 ]
Klingeler, R. [4 ]
Hess, C. [4 ]
Behr, G. [4 ]
Kondrat, A. [4 ]
Buechner, B. [4 ]
机构
[1] Helmholtz Zentrum Berlin Mat & Energie HZB, D-14109 Berlin, Germany
[2] Inst Max von Laue Paul Langevin, F-38042 Grenoble 9, France
[3] Inst Max Von Laue Paul Langevin, Forschungszentrum Julich Outstn, JCNS, F-38042 Grenoble 9, France
[4] Leibniz Inst Solid State & Mat Res IFW, Dresden, Germany
关键词
D O I
10.1103/PhysRevB.78.140503
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report the structure and magnetism of PrFeAsO, one of the parent phases of the Fe-As family of superconductors, as measured by neutron powder diffraction. In common with other REFeAsO materials, a tetragonal-orthorhombic phase transition is found on cooling below 136 K and striped Fe magnetism with k=(1,0,1) is detected below similar to 85 K. Our magnetic order-parameter measurements show that the ordered Fe moment along the a axis reaches a maximum at similar to 40 K, below which an anomalous expansion of the c axis sets in that results in a negative thermal volume expansion of 0.015% at 2 K. We propose that this effect, which is suppressed in superconducting samples, is driven by a delicate interplay between Fe and Pr ordered moments.
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页数:4
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