A cis-octahedral dichloro complex of Fe-III with a tetradentate dipyridyl-diamino ligand

被引：7

作者：

Alcock, NW ^{[1
]}

RybakAkimova, EV ^{[1
]}

Busch, DH ^{[1
]}

机构：

[1] UNIV KANSAS,DEPT CHEM,LAWRENCE,KS 66045

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270197004459

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In [N,N'-bis(2-pyridylmethyl)-1, 3-propanediamine-N,N',N '',N''']dichloroiron(III) perchlorate, [FeCl2(C15H20N4)]ClO4, the linear tetradentate Ligand adopts the cis-beta configuration which provides a favourable geometry for the six-membered chelate ring. The Fe-N distances show lengthening from the trans influence of the chloride ligands, with Fe-N-py values of 2.152 (3) and 2.179 (3) Angstrom, and Fe-N-amine distances of 2.141 (4) and 2.178 (4) Angstrom.

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页码：1385 / 1387

页数：3

相关论文

共 18 条

[1] MONONUCLEAR AND BINUCLEAR OXO-BRIDGED IRON(III) COMPLEXES OF N,N'-BIS(2-PYRIDYLMETHYL)ETHANE-1,2-DIAMINE (BISPICEN) [J].

ARULSAMY, N ;

HODGSON, DJ ;

GLERUP, J .

INORGANICA CHIMICA ACTA, 1993, 209 (01) :61-69

[2] BINUCLEAR OXO-BRIDGED IRON(III) COMPLEXES OF N,N'-BIS(2-PYRIDYLMETHYL)ETHANE-1,2-DIAMINE (BISPICEN) AND RELATED LIGANDS [J].

ARULSAMY, N ;

GOODSON, PA ;

HODGSON, DJ ;

GLERUP, J ;

MICHELSEN, K .

INORGANICA CHIMICA ACTA, 1994, 216 (1-2) :21-29

[3] A REALISTIC MODEL FOR HEME-CONTAINING CATALASES AND PEROXIDASES - THE X-RAY STRUCTURAL CHARACTERIZATION OF A NONPORPHYRIN IRON(III) MACROCYCLIC COMPLEX, AND THE MECHANISM OF ITS PEROXIDATION OF AROMATIC SUBSTRATES [J].

CAIRNS, CJ ;

HECKMAN, RA ;

MELNYK, AC ;

DAVIS, WM ;

BUSCH, DH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (11) :2505-2510

[4] A NITROGEN-GAS-STREAM CRYOSTAT FOR GENERAL X-RAY-DIFFRACTION STUDIES [J].

COSIER, J ;

GLAZER, AM .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1986, 19 (02) :105-107

[5] STERIC CONSTRAINTS IN FACULTATIVE LIGANDS - STEREOCHEMISTRY OF COBALT(III), NICKEL(II), COPPER(II), AND PALLADIUM(II) COMPOUNDS OF 2 HOMOLOGOUS TETRA-AMINES WITH TERMINAL PYRIDYL RESIDUES [J].

GIBSON, JG ;

MCKENZIE, ED .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (11) :1666-&

[6] DESIGN, SYNTHESIS, AND CHARACTERIZATION OF BIS(MU-OXO)DIMANGANESE(III,III) COMPLEXES - STERIC AND ELECTRONIC CONTROL OF REDOX POTENTIALS [J].

GOODSON, PA ;

OKI, AR ;

GLERUP, J ;

HODGSON, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (17) :6248-6254

[7] QUADRIDENTATE CHELATE COMPOUNDS .2. [J].

GOODWIN, HA ;

LIONS, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (19) :5013-5023

[8] TETRANUCLEAR HETEROMETALLIC COMPLEXES OF THE GENERAL TYPES [M((OH)2CRA4)3]5+ AND [M((OH)2COA4)3]5+ [J].

HODGSON, DJ ;

MICHELSEN, K ;

PEDERSEN, E ;

TOWLE, DK .

INORGANIC CHEMISTRY, 1991, 30 (04) :815-822

[9] SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES OF (MU-OXO)DIIRON(III) COMPLEXES RELATED TO DIIRON-OXO PROTEINS - STRUCTURE OF [FE2O(TPA)(2)(MOO4)](CLO4)(2) [J].

HOLZ, RC ;

ELGREN, TE ;

PEARCE, LL ;

ZHANG, JH ;

OCONNOR, CJ ;

QUE, L .

INORGANIC CHEMISTRY, 1993, 32 (25) :5844-5850

[10] ALKANE FUNCTIONALIZATION AT (MU-OXO)DIIRON(III) CENTERS [J].

LEISING, RA ;

KIM, JH ;

PEREZ, MA ;

QUE, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) :9524-9530