A cis-octahedral dichloro complex of Fe-III with a tetradentate dipyridyl-diamino ligand

被引：7

作者：

Alcock, NW ^{[1
]}

RybakAkimova, EV ^{[1
]}

Busch, DH ^{[1
]}

机构：

[1] UNIV KANSAS,DEPT CHEM,LAWRENCE,KS 66045

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270197004459

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In [N,N'-bis(2-pyridylmethyl)-1, 3-propanediamine-N,N',N '',N''']dichloroiron(III) perchlorate, [FeCl2(C15H20N4)]ClO4, the linear tetradentate Ligand adopts the cis-beta configuration which provides a favourable geometry for the six-membered chelate ring. The Fe-N distances show lengthening from the trans influence of the chloride ligands, with Fe-N-py values of 2.152 (3) and 2.179 (3) Angstrom, and Fe-N-amine distances of 2.141 (4) and 2.178 (4) Angstrom.

引用

页码：1385 / 1387

页数：3

共 18 条

[11] CATALYSIS OF THE DECOMPOSITION OF HYDROGEN-PEROXIDE BY A COMPLEX OF IRON(III) WITH A SYNTHETIC MACROCYCLIC LIGAND [J].