Mild and efficient palladium(II)-catalyzed racemization of allenes

被引：42

作者：

Horváth, A ^{[1
]}

Bäckvall, JE ^{[1
]}

机构：

[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 08期

关键词：

D O I：

10.1039/b316482a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allenes undergo racemization in the presence of catalytic amounts of Pd(OAC)(2)/LiBr under mild conditions; the reaction proceeds via a bromopalladation-debromopalladation sequence and tolerates various functional groups.

引用

页码：964 / 965

页数：2

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