Synthesis of diazadibenzo-18-crown-6 ligands with appended chromophoric and fluorophoric groups as potential metal ion chemosensors

被引：15

作者：

Xue, GP ^{[1
]}

Savage, PB ^{[1
]}

Krakowiak, KE ^{[1
]}

Izatt, RM ^{[1
]}

Bradshaw, JS ^{[1
]}

机构：

[1] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2001年 / 38卷 / 06期

关键词：

D O I：

10.1002/jhet.5570380631

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Six new diazadibenzo-18-crown-6 ligands substituted with two each of 8-hydroxyquinoline (7), 8-aminoquinoline (attached through its C-2 or C-7 position) (12 and 13). 8-methoxyquinoline (18), 5-chloro-8-methoxyquinoline (19), and dansylamidoethyl (21) side arms were synthesized as potential metal ion chemosensors and potential reagents for the selective extraction of certain metal ions from aqueous solutions. Ligands 7, 12, 13, 18, and 19 were synthesized by reductive amination of diazadibenzo-18-crown-6 (5) and the appropriate quinolinecarboxaldehydes. Bis(dansylamidoethyl)-substituted ligand 21 was synthesized by treating diazacrown ether 5 with N-dansylaziridine (20).

引用

页码：1453 / 1457

页数：5

共 22 条

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