Highly regio- and enantio-selective rhodium-catalysed asymmetric hydroformylation without organic solvents

被引：121

作者：

Franciò, G ^{[1
]}

Leitner, W ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904281d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High enantioselectivity and unprecedented high regioselectivity without the need for hazardous organic solvents are achieved in rhodium-catalysed asymmetric hydroformylation with the perfluoroalkyl-substituted ligand (R,S)-3-H(2)F(6)-BINAPHOS, whereby the substitution pattern of the ligand is crucial for its successful use in compressed carbon dioxide and for the increased regioselectivity.

引用

页码：1663 / 1664

页数：2

共 26 条

[1] ASYMMETRIC HYDROFORMYLATION [J].

AGBOSSOU, F ;

CARPENTIER, JF ;

MORTREAUX, A .

CHEMICAL REVIEWS, 1995, 95 (07) :2485-2506

[2]

[Anonymous], 1999, CHEM SYNTHESIS USING

[3] Hydroformylation of hex-1-ene in supercritical carbon dioxide catalysed by rhodium trialkylphosphine complexes [J].

Bach, I ;

Cole-Hamilton, DJ .

CHEMICAL COMMUNICATIONS, 1998, (14) :1463-1464

[4]

BANET A, 1998, 11 INT S HOM CAT ST, P252

[5] ASYMMETRIC CATALYTIC-HYDROGENATION REACTIONS IN SUPERCRITICAL CARBON-DIOXIDE [J].

BURK, MJ ;

FENG, SG ;

GROSS, MF ;

TUMAS, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (31) :8277-8278

[6] Electronically dissymmetric DIPHOS derivatives give higher n:i regioselectivity in rhodium-catalyzed hydroformylation than either of their symmetric counterparts [J].

Casey, CP ;

Paulsen, EL ;

Beuttenmueller, EW ;

Proft, BR ;

Matter, BA ;

Powell, DR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (01) :63-70

[7]

CONSIGLIO G, 1993, CATALYTIC ASYMMETRIC, P273

[8]

DINJUS E, 1996, CHEM EXTREME NONCLAS, P219

[9] Olefin metathesis in compressed carbon dioxide [J].

Furstner, A ;

Koch, D ;

Langemann, K ;

Leitner, W ;

Six, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (22) :2466-2469

[10] Hydroformylation of propylene in supercritical carbon dioxide [J].

Guo, Y ;

Akgerman, A .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (11) :4581-4585

← 1 2 3 →