Highly regio- and enantio-selective rhodium-catalysed asymmetric hydroformylation without organic solvents

被引：121

作者：

Franciò, G ^{[1
]}

Leitner, W ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904281d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High enantioselectivity and unprecedented high regioselectivity without the need for hazardous organic solvents are achieved in rhodium-catalysed asymmetric hydroformylation with the perfluoroalkyl-substituted ligand (R,S)-3-H(2)F(6)-BINAPHOS, whereby the substitution pattern of the ligand is crucial for its successful use in compressed carbon dioxide and for the increased regioselectivity.

引用

页码：1663 / 1664

页数：2

共 26 条

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