Extension of nanothermodynamics to include a one-dimensional surface excess

被引：42

作者：

Hill, TL ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

来源：

NANO LETTERS | 2001年 / 1卷 / 03期

关键词：

D O I：

10.1021/nl010009e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The problem of a long one-dimensional adsorbed lattice gas, with an adsorbent molecule at one end that creates a local mean surface excess, is recast as an example of nanothermodynamics: the surface excess itself (calculated by use of a reference system) can be viewed as a small thermodynamic system.

引用

页码：159 / 160

页数：2

共 4 条

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[2]

Hill T. L., 1994, Thermodynamics of Small Systems

[3] Extension of the thermodynamics of small systems to open metastable states: An example [J].

Hill, TL ;

Chamberlin, RV .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1998, 95 (22) :12779-12782

[4] Adsorption from a one-dimensional lattice gas and the Brunauer-Emmett-Teller equation [J].

Hill, TL .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1996, 93 (25) :14328-14332

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