Synthesis of an aspidosperma alkaloid precursor:: synthesis of (+)-aspidospermidine

被引：35

作者：

Gnecco, D ^{[1
]}

Vázquez, E

Galindo, A

Terán, JL

Orea, L

Bernès, S

Enríquez, RG

机构：

[1] BUAP, Inst Ciencias, Ctr Quim, 14 Sur 6301,Ciudad Univ Puebla, Puebla 72570, Mexico

[2] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

ARKIVOC | 2003年

关键词：

alkaloids; hydrolulolidone; (+)-aspidospermidine;

D O I：

10.3998/ark.5550190.0004.b19

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The aspidosperma alkaloid precursor (-)-(4aR,8aS,8R)-4a-ethyl-decahydroquinolin-7-one 7 (hydrolilolidone) was prepared from (+)-(1'S,4aR, 8aS)- 4a-ethyl-1-(1'-phenylethyl)octahydroquinolin-7-one 3. In addition, a synthesis of (+)- aspidospermidine 9 using compound 7 as starting material is described.

引用

页码：185 / 192

页数：8

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