Microstructures of two-stage aluminized coatings on Inconel 600

被引：34

作者：

Chien, A ^{[1
]}

Gan, D ^{[1
]}

Shen, P ^{[1
]}

机构：

[1] NATL SUN YAT SEN UNIV, INST MAT SCI & ENGN, KAOHSIUNG 80424, TAIWAN

来源：

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 1996年 / 206卷 / 02期

关键词：

aluminized coating; inconel; 600; transmission electron microscopy; microstructures;

D O I：

10.1016/0921-5093(95)09899-2

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Two-stage aluminized coatings on a nickel-base alloy, Inconel 600, are prepared by aluminizing at 850 degrees C and then annealing at 1050 degrees C. In the first-stage coating, a planar layer of sigma phase forms between the gamma substrate and the nickel-rich beta-NiAl the coating matrix near the interface. Being chromium-, iron-, and nickel-rich but aluminum-poor, the a phase layer can act as a diffusion barrier for aluminizing, and the diffusion of aluminum can proceed across the a phase only through the grain boundaries. In the second-stage coating the interfacial sigma phase breaks down into a zone containing a beta phase and Cr23C6 carbide. An amorphous phase with CrC carbide is formed near the interface in both stages. Chromium aluminides are found to precipitate in alpha-Cr in both stage coatings and in beta-NiAl in the second-stage coating. In the first-stage coating, fine Cr5Al8 particles precipitate in alpha-Cr particles and the crystallographic relationship between them is [001](Cr5Cl8)parallel to[001](alpha-Cr) and [110](Cr5Al8)parallel to[110](alpha-Cr). In the second-stage coating, Cr2Al precipitates in alpha-Cr particles and bears an orientation relationship of [010](Cr2Al8)parallel to[010](alpha-Cr) and [001](Cr2Al)parallel to[001](alpha-Cr). Cr2Al also precipitates in the beta-NiAl matrix with an orientation relationship of [010](Cr2Al)parallel to[010](NiAl) and [001](Cr2Al)parallel to[001](NiAl).

引用

页码：215 / 224

页数：10

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