Interactions and coalescence of nanodroplets in translucent O/W emulsions

被引:33
作者
Sing, AJF
Graciaa, A
Lachaise, J [1 ]
Brochette, P
Salager, JL
机构
[1] Univ Pau & Pays Adour, Lab Thermodynam Etats Metastables & Phys Mol, F-64000 Pau, France
[2] ELF Aquitaine Co, Grp Rech Lacq, Serv Chim Phys, F-64170 Artix, France
[3] Univ Los Andes, Lab Fenomenos Interfaciales & Recuperac & Petrole, Merida, Venezuela
关键词
coalescence; hard spheres; light scattering; mini-emulsions; nanodroplets; structure factor; translucent emulsions;
D O I
10.1016/S0927-7757(98)00622-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A thermal protocol has allowed us to produce translucent O/W emulsions composed of nanodroplets. By means of a static light scattering analysis, we show that the interaction potential existing between nanodroplets is practically a hard sphere interaction potential. Dynamic light scattering measurements bring us to study the steric effect induced by the surfactant molecules which are adsorbed at the water/oil interface. We confirm that nanodroplet dynamic coalescence rates are slowed down when the surfactant molecular weight is high. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:31 / 39
页数:9
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