Fragmentation and intracluster reactions of hydrated aluminum cations Al+(H2O)(n), n=3-50

被引：107

作者：

Beyer, M ^{[1
]}

Berg, C ^{[1
]}

Gorlitzer, HW ^{[1
]}

Schindler, T ^{[1
]}

Achatz, U ^{[1
]}

Albert, G ^{[1
]}

NiednerSchatteburg, G ^{[1
]}

Bondybey, VE ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST THEORET & PHYS CHEM,D-85747 GARCHING,GERMANY

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1996年 / 118卷 / 31期

关键词：

D O I：

10.1021/ja9606438

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrated aluminum cluster cations Al+(HO2)(n) with n=3-50 were stored in a collision-free environment, and their unimolecular fragmentation induced by the room temperature ''black body'' infrared background was studied. An interesting size-dependent intracluster reaction resulting in oxidation of the aluminum cation and elimination of molecular hydrogen was observed. The results are discussed and compared with similar recent studies of hydrated magnesium clusters.

引用

页码：7386 / 7389

页数：4

共 17 条

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