Highly diastereoselective synthesis of decalin skeletons with quaternary carbon centers via the tandem oxy-cope/ene/Claisen reaction

被引：36

作者：

Barriault, L ^{[1
]}

Denissova, I ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 08期

关键词：

D O I：

10.1021/ol025694q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The highly diastereoselective cascade sequence of three successive thermal pericyclic reactions of 1,2-divinylcyclohexanol allyl and propargyl ethers is described. This novel tandem process provides an efficient synthesis of sesqui- and diterpenoid skeletons having a quaternary carbon at C9.

引用

页码：1371 / 1374

页数：4

共 23 条

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