Spontaneous anti-resolution in heterochiral clusters of serine

被引：37

作者：

Julian, RR ^{[1
]}

Myung, S ^{[1
]}

Clemmer, DE ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 13期

关键词：

D O I：

10.1021/ja031516w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chirality plays an important role in the formation and stability of noncovalent clusters which are made of chiral molecules. It is shown that clusters can exhibit a preference for both homochirality and heterochirality. Serine cluster formation is dominated by the formation of heterochiral aggregates, with the exception of the previously observed homochiral serine octamer. Thus, the majority of serine clusters lead to chiral anti-resolution, or the racemic mixing of enantiomers. Copyright © 2004 American Chemical Society.

引用

页码：4110 / 4111

页数：2

共 19 条

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[2]

2-0

[3]

Clemmer DE, 1997, J MASS SPECTROM, V32, P577

[4] Chiroselective self-directed octamerization of serine: Implications for homochirogenesis [J].