Interpolymer complexes of copolymers of vinyl ether of diethylene glycol with poly(acrylic acid)

被引：32

作者：

Mun, GA ^{[1
]}

Nurkeeva, ZS ^{[1
]}

Khutoryanskiy, VV ^{[1
]}

Sergaziyev, AD ^{[1
]}

机构：

[1] Kazakh State Natl Univ, Dept Macromol Chem, Almaty 480012, Kazakhstan

来源：

COLLOID AND POLYMER SCIENCE | 2002年 / 280卷 / 03期

关键词：

interpolymer complexes; hydrophobic-hydrophilic balance; critical pH; stability;

D O I：

10.1007/s00396-001-0609-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The complex formation reactions of poly(vinyl ether of diethylene glycol) as well as vinyl ether of diethylene glycol-vinyl butyl ether copolymers with poly(acrylic acid) have been studied in aqueous and alcohol solutions. The formation of interpolymer complexes which were stabilized by hydrogen bonds was shown. The effects of molecular weight of poly(acrylic acid) and the nature of the nonionic polymer on the composition and stability of interpolymer complexes were clarified. The critical pH values of complexation were determined for different systems with various molecular weights and hydrophobic-hydrophilic balances. The stability of the interpolymer complexes formed in aqueous and alcohol solutions with respect to dimethylformamide addition was evaluated. The role of hydrophobic interactions and the presence of active groups on stability of the interpolymer complexes is discussed.

引用

页码：282 / 289

页数：8

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