Shape Control of Cobalt Carbonate Particles by a Hydrothermal Process in a Mixed Solvent: An Efficient Precursor to Nanoporous Cobalt Oxide Architectures and Their Sensing Property

被引:152
作者
Cong, Huai-Ping [1 ]
Yu, Shu-Hong [1 ]
机构
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Struct Res Lab CAS, Div Nanomat & Chem,Hefei Natl Lab Phys Sci Micros, Hefei 230026, Peoples R China
基金
美国国家科学基金会;
关键词
FIELD-EMISSION PROPERTIES; HIGH-YIELD SYNTHESIS; SOLVOTHERMAL SYNTHESIS; MAGNETIC-PROPERTIES; MORPHOLOGY CONTROL; CALCIUM-CARBONATE; ORIENTED ATTACHMENT; CO3O4; NANOWIRES; FABRICATION;
D O I
10.1021/cg8003068
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Shape-controlled synthesis of CoCO3 crystals has been achieved by a hydrothermal process in a mixed solvent of water and ethanol (or glycerol). Uniform CoCO3 crystals with novel structures can be fabricated by tuning the volume ratio of water and ethanol (or glycerol). The results demonstrated that the as-prepared CoCO3 crystal can act as an efficient precursor for production of nanoporous Co3O4 particles with pore sizes of 2.5 and 60 nm by calcination at 500 degrees C. The nanoporous Co3O4 Particles show sensitive response and reversibility in sensing performance.
引用
收藏
页码:210 / 217
页数:8
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