Design of Heterocomplementary H-Bonding RAFT Agents - Towards the Generation of Supramolecular Star Polymers

被引：48

作者：

Bernard, Julien ^{[1
,2
,3
]}

Lortie, Frederic ^{[1
,2
,3
]}

Fenet, Bernard ^{[4
]}

机构：

[1] Univ Lyon, F-69003 Lyon, France

[2] Inst Natl Sci Appl, IMP LMM, F-69621 Villeurbanne, France

[3] CNRS, UMR Ingenierie Mat Polymeres 5223, F-69621 Villeurbanne, France

[4] ESCPE Lyon, RMN UCB Lyon1, Ctr Commun, F-69616 Villeurbanne, France

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2009年 / 30卷 / 02期

关键词：

hydrogen-bonding; poly(vinyl acetate); reversible addition-fragmentation chain transfer; star polymers; supramolecular structures; RADICAL POLYMERIZATION; SUBSTITUENTS;

D O I：

10.1002/marc.200800586

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Supramolecular poly(vinyl acetate) PVAc 3-arms stars were successfully generated by Reversible Addition-Fragmentation chain Transfer (RAFT)-polymerized chains bearing hydrogen-bonding heterocomplementary associating units. Chain Transfer Agents (CTA) bearing thymine- and diaminopyridine-based units were first synthesized and proved to mediate efficiently the polymerization of VAc. The binding ability of the chains in solution was then demonstrated by H-1 NMR and GPC measurements, proving the formation of the supramolecular stars.

引用

页码：83 / 88

页数：6

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[32] Synthesis and assembly of self-complementary calix[4]arenes [J].