Desorption of LiAlH4 with Ti- and V-based additives

被引：112

作者：

Blanchard, D

Brinks, HW

Hauback, BC

Norby, P

机构：

[1] Inst Energy Technol, Dept Phys, NO-2027 Kjeller, Norway

[2] Univ Oslo, N-0315 Oslo, Norway

来源：

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2004年 / 108卷 / 1-2期

关键词：

hydrogen storage; lithium aluminium hydride; alanate; ball-milling;

D O I：

10.1016/j.mseb.2003.10.114

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Thermal desorption spectroscopy and X-ray diffraction experiments show that ball-milling of LiAlD4 in presence of VCl3 or TiCl3 (.) 1/3(AlCl3) can reduce its thermal decomposition temperatures by 60 and 50degreesC, respectively. However, some partial decomposition of LiAlD4 into Li-3 AlD6, Al and D-2 occurs during the mechanical processing: 80% for TiCl(3)(.)1/3(AlCl3), 40% for VCl3. LiCl is formed during the ball-milling, this suggests the reduction of the additives by LiAlD4. The localisations of Ti or V atoms are not yet determined. (C) 2003 Elsevier B.V. All rights reserved.

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收藏

页码：54 / 59

页数：6

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