Recent Insights into Manganese Oxides in Catalyzing Oxygen Reduction Kinetics

被引：379

作者：

Stoerzinger, Kelsey A. ^{[1
]}

Risch, Marcel ^{[2
]}

Han, Binghong ^{[1
]}

Shao-Horn, Yang ^{[1
,2
,3
]}

机构：

[1] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA

[2] MIT, Elect Res Lab, Cambridge, MA 02139 USA

[3] MIT, Dept Mech Engn, Cambridge, MA 02139 USA

来源：

ACS CATALYSIS | 2015年 / 5卷 / 10期

基金：

美国国家科学基金会;

关键词：

manganese oxide; electrocatalysis; oxygen reduction reaction; alkaline; valence; peroxide disproportionation; HYDROGEN-PEROXIDE DECOMPOSITION; METAL-AIR BATTERIES; RING-DISK ELECTRODE; ENHANCED ELECTROCATALYTIC ACTIVITY; ELECTROCHEMICAL WATER OXIDATION; RAY-ABSORPTION SPECTROSCOPY; PROTON-EXCHANGE MEMBRANE; JAHN-TELLER DISTORTION; PEROVSKITE-TYPE OXIDES; ALKALINE MEDIA;

D O I：

10.1021/acscatal.5b01444

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The sluggish kinetics of the oxygen reduction reaction (ORR) limit the efficiency of numerous oxygen-based energy conversion devices such as fuel cells and metal-air batteries. Among earth abundant catalysts, manganese-based oxides have the highest activities approaching that of precious metals. In this Review, we summarize and analyze literature findings to highlight key parameters that influence the catalysis of the ORR on manganese-based oxides, including the number of electrons transferred as well as specific and mass activities. These insights can help develop design guides for highly active ORR catalysts and shape future fundamental research to gain new knowledge regarding the molecular mechanism of ORR catalysis.

引用

页码：6021 / 6031

页数：11

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